Which Is Not Protection Again Poisonous Gases
Run a risk Controls
The Risk Control Plan for your lab's procedures involving hazardous gases will detail specific technology controls, work practices, or personal protective equipment that is required.
Some full general guidance for chancy gas use is given below.
Engineering Controls
All components of a organization connected to a compressed gas cylinder must be pressure-rated to withstand the maximum pressure capable of being delivered by the cylinder or the maximum output pressure of the regulator that is connected to the cylinder valve.
Fume hood
Work with hazardous gases must be performed inside of a fume hood or with another means of defended exhaust that has been reviewed and approved by EHRS.
Safety shielding
Safety shielding is required whatever time in that location is a risk of explosion, splash hazard or a highly exothermic reaction. All manipulations of chancy gases which pose this risk should occur in a fume hood with the sash in the lowest viable position.
Glove (dry) box
Some processes involving acutely toxic gases may exist performed in a properly vented glove box rather than a fume hood.
Gas Alarms
Continuous-monitoring gas alert systems are required for some chancy gases. EHRS volition assess the need for gas monitoring as part of the take a chance assessment that volition be done before approving use of the hazardous gas.
Regulators
A two-stage regulator is a device that reduces the higher pressure in the gas cylinder to a lower working pressure. Two stage regulators control force per unit area in two steps allowing precise control of pressure.
A two-stage regulator is required for dispensing gas from high-pressure gas cylinders. The regulator must be uniform with the gas and with the intended apply. The maximum pressure of the second stage of the regulator should be as depression every bit is practical for the intended experimental work.
The Compressed Gas Association (CGA) recommends that regulators exist refurbished every v years.
Flow-control valves
A mechanical flow-control valve (needle valve) that is uniform and properly cleaned for the chancy gas must exist attached directly to the gas outlet of the gas regulator. This is required even if other menses control devices are nowadays in the experimental device. Flow control must non be attempted through utilize of the gas regulator or cylinder valve. A flow-control valve controls therate of gas flow (e.g. liters per minute), whereas a force per unit area regulator controls thegas pressure(e.g. pounds per square inch).
Flow-restricting orifices
A period-restricting orifice is a period-limiting devices that restricts the maximum flow out of a compressed gas regulator. These devices are typically critical orifices.
Where feasible, flow restricting devices must exist installed after the regulator. Select the appropriate flow restricting orifice based on gas used and the flow charge per unit required for the research. Your lab'south task-specific Hazard Control Plan must specify whether a period-restricting orifice is required for your hazardous gas utilise.
Tubing and piping
Hazardous gases must exist dispensed using systems that are properly cleaned and compatible with the gas in apply. Burst pressure of tubing and piping must exceed the maximum pressure on the second stage regulator. Exceptions to this requirement may be fabricated for short sections of tubing when information technology, and the compressed gas cylinder, are completely enclosed in a fume hood and depression pressures and flow rates are used. Tubing and piping used with flammable gases may non be combustible. Flexible pipage must exist kept as short every bit possible and should not exceed 5 feet.
Acetylene and ammonia cannot come in contact with "red metal" (copper content >65%). Stainless steel must be used for pipage these gases and acetylene-specific regulators must be used
Purge assembly
A purge assembly is a valving system that permits the flushing of the regulator and delivery tubing with inert gas.
A purge assembly is required whenever a hazardous gas system is not completely housed within a ventilated enclosure. Purge assemblies must exhaust into a fume hood or other approved exhaust organisation. Exceptions may exist made for laser systems that contain pocket-sized quantities of hazardous gas that will be effectively filtered when exhausted. Exemptions must be approved by EHRS.
Check valve
A check valve maintains positive pressure in the line when you disconnect from the cylinder. This prevents gas from escaping the process line and prevents air from entering the process line.

Backlog-flow valve
An excess-flow valve is a mechanical device that detects backlog flow, which would indicate a leak in the pipe, and shuts off the flow. At that place are ii varieties: Ane that is re-settable after activation and one that requires a special key to reset it after an incident. Excess-menses valves generally aren't used with corrosive gases considering they would become corroded. The valve should be located in-line equally close to the cylinder as possible.

Flame arrestors and flash-back arrestors
The following clarification is taken from TWI'south article What is a flame or Flashback Arrestor? (accessed 6/25/2021)
A flame or flashback arrestor is a safety device designed to stop a flame in its tracks. It is therefore used to prevent flashback into cylinders or pipework.
The flame arrestor commonly contains an element which may consist of narrow passages through a wire mesh or metal cream. When a flame enters the element, it is quickly cooled by the common cold surface of the element and the flame is extinguished. The flame arrestor may comprise a pressure level or temperature actuated cut-off valve, and may and then be known equally a flashback arrestor.
Over-pressure protection
Applied science controls for over-pressure level protection include force per unit area-relief valves, rupture disks, hydrostatic head devices, and high-force per unit area shutdown devices.
Vacuum pumps
Hydrocarbon based vacuum pump oil is incompatible with strongly oxidizing and many reactive gases. New vacuum pumps that take inert lubricants such as DuPont Krytox and never contained oil-based lubricants must be used with oxidizing and reactive gases. Vacuum pumps must be deeply vented to a fume hood or other approved exhaust system with tubing that is compatible with the gases used. Exhaust lines must be as curt as feasible. Vented enclosures may be required for vacuum pumps depending on the toxicity of the gases used.
Piece of work Practices
A list of recommended work practices for hazardous chemic handling is included in Section Five: Chemical Handling in this CHP.
Work Practice guidance for compressed gases is given in SOP: Compressed Gases. All requirements for storage, transport, and securing of gas cylinders apply to chancy gases.
Specific Work Practices for Hazardous Gases
Boosted work practices for reducing the risks of any lab procedure involving chancy gasesmust be described in a written Take chances Command Plan.
Administrative controls (work practices) are not sufficient controls for preventing explosive and incompatible gas mixtures in manifolded systems. Engineering controls and proper apparatus design must exist used to forbid mixing of incompatible gases within the system.
Considerations for purchase
Purchase the smallest volume of hazardous gas needed for near-term research needs (approximately 3 months). While the initial purchase cost per cubic foot may be lower when hazardous gases are purchased in full sized cylinders, the overall cost of experimental setup (which may require local ventilation, gas cabinets, stainless steel piping and purging systems) may starting time the credible saving from ownership hazardous gases in full sized cylinders.
Hazardous gases that are used in low concentrations (mixed with inert gases) must exist purchased as pre-mixed whenever possible.
Mixtures of combustible and oxidizing gases may not be purchased and must not exist mixed in procedure. If mixing of flammable and oxidizing gases is required for your research, contact EHRS, See this Safety Alert for more information about this gamble.
Connections
CGA fittings must be compatible with the gas. Do non apply adapters or modify regulator or connectors.
Left-handed or "reversed" tread connections are used with flammables, corrosives, and air.
Right-handed thread connections are used with toxic gases.
Minimize the number of connections between the regulator outlet and the betoken of utilise.
Teflon tape must not exist used with Swagelock or CGA fittings.
Gaskets are usually used in CGA connections with corrosive gases. The gasket must be changed at least in one case every 3 cylinder changes. The gaskets are required to create a gas-tight seal. It's important to have extra gaskets available in the lab.
Leak testing
Hazardous gas systems must be leak tested using inert gas and leak detection solutions such equally Snoop(TM) before utilise.
Gas trapping and Scrubbing
To prevent ecology pollution and damage to equipment it may exist necessary to trap and or scrub exhaust from processes which employ corrosive gases even when working in the fume hood. Contact EHRS for help with design and set-up of gas neutralization processes.
When corrosive gases are to exist discharged into a liquid, a trap, cheque valve, or vacuum intermission device must be employed to prevent dangerous reverse catamenia.
Purging
Regulators and valves must be closed when the cylinder is not in employ and flushed with dry air or nitrogen later on use.
All piping and tubing must be flushed with inert gas after process is consummate and earlier opening whatever component of the system to ambient air.
Piece of work practices for installing regulators
- First, tighten the regulator connectedness to the cylinder by hand, then use a ane.25" open up wrench to turn the connecting nut about thirty degrees.
- Close the flow control valve
- Open the cylinder valve completely to ensure information technology seals at the elevation of the valve
Personal Protective Equipment
Consider the potential routes of exposure and health consequences when selecting personal protective equipment (PPE) for tasks involving chancy gases.
In improver to the minimum lab apparel and PPE requirements, other protective equipment may be necessary to reduce risks. When additional equipment (such as tight-fitting chemical splash goggles, chemical-resistant gloves, or disposable lab coats) are required, a Hazard Control Programme must be written to document the gamble assessment and controls.
Contact EHRS for assistance with risk assessments, glove compatibility, and other PPE selection.
The minimum PPE requirements for all chemical treatment tasks, and information most specialty PPE tin can be establish in the "Personal Protective Equipment" department of Section Five: Chemical Handling in this CHP.
Source: https://ehrs.upenn.edu/health-safety/lab-safety/chemical-hygiene-plan/standard-operating-procedures/sop-hazardous-and
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